Triethyl 2-Fluoro-2-phosphonoacetate

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2-Fluoro-l-histidine

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In the title compound, C11H6FN3O5, the dihedral angle between the aromatic rings is 72.4 (3)°. The NO2 groups form dihedral angles of 40.8 (2) and 4.8 (2)°, respectively, with the attached pyridine and benzene rings. The crystal structure features π-π stacking between centrosymmetrically related pairs of pyridine rings [centroid-centroid separation = 3.800 (3) Å].

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2-Fluoro-N′-(2-meth­oxy­benzyl­idene)benzohydrazide

The mol-ecule of the title compound, C(15)H(13)FN(2)O(2), exists in a trans configuration with respect to the methyl-idene unit. The two benzene rings form a dihedral angle of of 64.7 (2)°. In the crystal, mol-ecules are linked through N-H⋯O hydrogen bonds into chains propagating along the c axis.

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ژورنال

عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan

سال: 1997

ISSN: 0037-9980,1883-6526

DOI: 10.5059/yukigoseikyokaishi.55.72